Yeah the 'highly scientific' bit I described earlier is total BS. Your result pretty much depends on my own little perception of which character was good with certain things and bad with others. There is no *best* answer really (yet another lie) so just have fun with it!
Stargate, Andromeda, Babylon 5, and (insert cheesy Sci-Fi show here) fans need not be hopeful as none of the characters from those shows will be considered here. Hell, Stargate spinoffs didnt even have a captain but I just wanted to lump that in with the other vile Sci-Fi cheese. There is but one non Star Trek captain outcome, and only one, and it's fairly predictable who that is.